I think a "less-smart" controller could be configured to work with these restrictions, but the Rachio can't be tweaked the same way. As @Modawg2k noted, your allowed watering can be interpreted as two days a week with a midnight to 6pm allowed time if your controller was set up for a time zone 16hrs ahead of your actual time zone. On a dumb controller, you'd manually set the date/time to make this happen. Since the Rachio uses latitude/longitude to automatically set your date/time AND figure out your closest weather station, you can't use the dumb controller time zone hack.
Since it is generally not recommended to water in the evening (promotes fungal growth and such overnight), I think you are best off just configuring your system to water on Tue/Fri with a start time of midnight or 1am (or later if you know your runtimes won't run into the 10am cutoff). I have flex daily set up with Wed/Sat allowed starting at 3am for spray zones, and those zones are done watering by 8am.